And for the excellent performance of pure phthalocyanine isomers in organic semiconductors, nonlinear optical material etc., researches on preparation of the four constitutional isomers of phthalocyanine complexes have become one of the hot areas. So this thesis is divided into the following two parts: 1. 并且,由于单一酞菁异构体在有机半导体、非线性光学材料等领域的优良性能,不对称酞菁四种结构异构体分离纯化研究已经成为热点之一。